Download The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers PDF Free

The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers PDF
By:Yuri Arsenovich Mikheev,Gennady Zaikov
Published on 2004-04-01 by CRC Press

The monograph is intended for elucidation of the novel trend in chemical physics regarding the polymer non-crystalline phase. It stresses the physical phenomena affecting the kinetics and mechanism of chemical reactions proceeding in the non-crystalline polymer matrix (NCPM). NCPM is depicted in terms of a supramolecular (carcass-micellar) model. The model is thought to reflect heterophase packing of polymeric chains, which co-operate as a molecular-chain sponge. The NCPM model presented is proved for adequate description of principal structure-physical phenomena to elaborate the scheme of structural-kinetic modeling of chemical reactions in bulky polymers. Structure-physical phenomena elucidated in the monograph are: - peculiarities of polymer plasticization and polymer blending with liquids; - structural and thermodynamic aspects of sorption of low molecular species; - properties of ESR (spin) probes and optical (molecular) probes; - features of water absorbed by polymers; - mechanical and thermal effects generated by the molecular-chain sponge; - supramolecular aspects of NCPM chemical physics. This monograph includes the structural-kinetic modeling of complex polymer chemical reactions. It deals with the problem of mechanism and kinetics of free radical chain reactions using thermal and photochemical model reactions of dibenzoyl peroxide with glassy-like polymers (cellulose triacetate, polycarbonate, polystyrene, polyamide PA-548), viscoelastic polymers (atactic polypropylene, polyamide PA-548, polyethylene, polyisobutylene, melted poly(ethylene oxide), and isotactic polypropylene. In all cases, the supramolecular heterophase mechanism of the processes, which was unknown for homogeneous systems, was proved. Furthermore, heterophase mechanisms of photochemical reaction between naphthalene and cellulose triacetate and photolysis of poly(methyl methacrylate) proceeding as a photochain reaction are indicated.

This Book was ranked at 29 by Google Books for keyword Chemical Physics.

Book ID of The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers's Books is 4fZ45vAEf34C, Book which was written byYuri Arsenovich Mikheev,Gennady Zaikovhave ETAG "6D3DV6N1lIg"

Book which was published by CRC Press since 2004-04-01 have ISBNs, ISBN 13 Code is 9789067644020 and ISBN 10 Code is 9067644021

Reading Mode in Text Status is false and Reading Mode in Image Status is true

Book which have "450 Pages" is Printed at BOOK under CategoryTechnology and Engineering

Book was written in en

eBook Version Availability Status at PDF is falseand in ePub is false

Book Preview

Download The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers PDF Free

Download The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers Books Free

Download The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers Free

Download The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers PDF

Download The Concept of Micellar-Sponge Nanophases in Chemical Physics of Polymers Books